Xiangyang Guo（郭向阳）Associate ProfessorDalian National Laboratory for Clean Energy and State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Dalian, China, 116023E-mail: xyguo@dicp.ac.cnEducational Experience:2007-2011, Bachelor degree (Applied Chemistry), Henan University2012-2018, Ph. D. (Applied Chemistry), State Key Laboratory of Fine Chemicals, Dalian University of Technology2018-2022, Assistant Researcher, Dalian Institute of Chemical Physics2022-present, Associate Professor, Dalian Institute of Chemical PhysicsResearch Interests:1. Research on the application of wide-spectrum light-harvesting metal-organic frameworks in photocatalysis. Based on coordination chemistry theory, design and synthesize water-phase stable wide-spectrum light-harvesting metal-organic framework materials using molecular engineering and crystal engineering strategies; carry out research on solar photocatalytic water splitting, carbon dioxide reduction, and nitrate reduction; explore the "structure-property" relationship of catalytic systems through the explicit structure of metal-organic framework materials to provide ideas for the development of new MOF-based catalyst materials for efficient solar energy photochemical conversion.2. Research on the application of conductive metal-organic frameworks in electrocatalysis.Using the tunable and controllable characteristics of metal-organic framework structures, develop new synthetic strategies for conductive metal-organic frameworks with catalytically active sites for carbon dioxide reduction, nitrate reduction, or nitrogen reduction; conduct electrocatalytic activation studies on small molecules such as CO2, NO3-, and N2; through advanced in-situ XAS-FTIR/Raman combined platforms, combined with the explicit structure of metal-organic frameworks to investigate the changes in metal-organic framework structures and the evolution rules of intermediate species during the electrocatalytic reaction process, guiding the design and synthesis of highly efficient and selective MOF-based new materials that reduce CO2, NO3-, and N2to high-value-added products.Pepresentative Publications:1. Li, Qinglin#; Luo, Lin#; Guo, Xiangyang#; Wang, Rong#; Liu, Jinfeng; Fan, Wenjun; Feng, Zhaochi; Zhang, Fuxiang*, Modulation of the second-beyond coordination structure in single-atom electrocatalysts for confirmed promotion of ammonia synthesis. Journal of the American Chemical Society 147(2), 1884-1892 (2025).2. Li, Sha; Lin, Jiande*; Wang, Huiqun; Zhou, Shiyuan; Guo, Xiangyang*; Zhan, Xiao; Tao, Hongwei; Hu, Haitao; He, Zhengyou; Liao, Honggang; Zhan, Dongping; Zhang, Li*, Three-dimensional metal–organic frameworks with selectively activated aromatic rings for high-capacity and high-rate lithium-ion storage. Angewandte Chemie International Edition 64, e202423186 (2025).3. Liu, Lifang; Du, Shiwen; Xiao, Yejun; Guo, Xiangyang; Jin, Shengye; Shao, Guosheng; Zhang, Fuxiang*, Saturated Ti-coordinated {001} facets-dependent photocatalytic water reduction over NH2-MIL-125(Ti) sheets: Observation and unraveling of facets effect. Applied Catalysis B: Environmental 338, 123094 (2023).4. Liu, Lifang#; Du, Shiwen#; Guo, Xiangyang#; Xiao, Yu; Yin, Zixi; Yang, Nengcong; Bao, Yunfeng; Zhu, Xunjin; Jin, Shengye; Feng, Zhaochi; Zhang, Fuxiang*, Water-stable nickel metal-organic framework nanobelts for cocatalyst-free photocatalytic water splitting to produce hydrogen. Journal of the American Chemistry Society 144, 2747-2754 (2022).5. Li, Sha; Lin, Jiande; Ding, Yu; Xu, Pan; Guo, Xiangyang*; Xiong, Weiming; Wu, Deyin; Dong, Quanfeng; Chen, Jiajia*; Zhang, Li*, Defects engineering of lightweight metal-organic frameworks-based electrocatalytic membrane for high-loading lithium-sulfur batteries. ACS Nano 15, 13803-13813 (2021).6. Guo, Xiangyang; Liu, Lifang; Xiao, Yu; Mehmood, Rashid; Xiao, Yejun; Qi, Yu; Zhang, Fuxiang*, Water-stable cobalt-based MOF for water oxidation in neutral aqueous solution: A case of mimicking the photosystem II. Inorganic Chemistry 60, 1790-1796 (2021).7. Guo, Xiangyang; Xiao Yu; Liu Lifang; Qi Yu; Duan Chunyng; Zhang Fuxiang*, Band gap engineering of metal-organic frameworks for solar fuel productions. Coordination Chemistry Reviews 435, 213785 (2021).8. Xiao, Yu#; Guo, Xiangyang#; Yang, Nengcong; Zhang, Fuxiang*, Heterostructured MOFs photocatalysts for water splitting to produce hydrogen. Journal of Energy Chemistry 58, 508–522 (2021).9. Zhang, Tiexin#; Guo, Xiangyang#; Shi, Yusheng; He, Cheng; Duan, Chunying*, Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions. Nature Communications 9, 4024 (2018).10.Guo, Xiangyang; Zhou, Zhen; Chen, Cong; Bai, Junfeng; He, Cheng; Duan, Chunying*, New rht-type metal-organic frameworks decorated with acylamide groups for efficient carbon dioxide capture and chemical fixation from raw power plant flue gas. ACS Applied Materials and Interfaces 8, 31746-31756 (2016).
Xiangyang Guo（郭向阳）
Associate Professor
Dalian National Laboratory for Clean Energy and State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Dalian, China, 116023
E-mail: xyguo@dicp.ac.cn
Educational Experience:
2007-2011, Bachelor degree (Applied Chemistry), Henan University
2012-2018, Ph. D. (Applied Chemistry), State Key Laboratory of Fine Chemicals, Dalian University of Technology
2018-2022, Assistant Researcher, Dalian Institute of Chemical Physics
2022-present, Associate Professor, Dalian Institute of Chemical Physics
Research Interests:
1. Research on the application of wide-spectrum light-harvesting metal-organic frameworks in photocatalysis.
Based on coordination chemistry theory, design and synthesize water-phase stable wide-spectrum light-harvesting metal-organic framework materials using molecular engineering and crystal engineering strategies; carry out research on solar photocatalytic water splitting, carbon dioxide reduction, and nitrate reduction; explore the "structure-property" relationship of catalytic systems through the explicit structure of metal-organic framework materials to provide ideas for the development of new MOF-based catalyst materials for efficient solar energy photochemical conversion.
2. Research on the application of conductive metal-organic frameworks in electrocatalysis.
Using the tunable and controllable characteristics of metal-organic framework structures, develop new synthetic strategies for conductive metal-organic frameworks with catalytically active sites for carbon dioxide reduction, nitrate reduction, or nitrogen reduction; conduct electrocatalytic activation studies on small molecules such as CO2, NO3-, and N2; through advanced in-situ XAS-FTIR/Raman combined platforms, combined with the explicit structure of metal-organic frameworks to investigate the changes in metal-organic framework structures and the evolution rules of intermediate species during the electrocatalytic reaction process, guiding the design and synthesis of highly efficient and selective MOF-based new materials that reduce CO2, NO3-, and N2to high-value-added products.
Pepresentative Publications:
1. Li, Qinglin#; Luo, Lin#; Guo, Xiangyang#; Wang, Rong#; Liu, Jinfeng; Fan, Wenjun; Feng, Zhaochi; Zhang, Fuxiang*, Modulation of the second-beyond coordination structure in single-atom electrocatalysts for confirmed promotion of ammonia synthesis. Journal of the American Chemical Society 147(2), 1884-1892 (2025).
2. Li, Sha; Lin, Jiande*; Wang, Huiqun; Zhou, Shiyuan; Guo, Xiangyang*; Zhan, Xiao; Tao, Hongwei; Hu, Haitao; He, Zhengyou; Liao, Honggang; Zhan, Dongping; Zhang, Li*, Three-dimensional metal–organic frameworks with selectively activated aromatic rings for high-capacity and high-rate lithium-ion storage. Angewandte Chemie International Edition 64, e202423186 (2025).
3. Liu, Lifang; Du, Shiwen; Xiao, Yejun; Guo, Xiangyang; Jin, Shengye; Shao, Guosheng; Zhang, Fuxiang*, Saturated Ti-coordinated {001} facets-dependent photocatalytic water reduction over NH2-MIL-125(Ti) sheets: Observation and unraveling of facets effect. Applied Catalysis B: Environmental 338, 123094 (2023).
4. Liu, Lifang#; Du, Shiwen#; Guo, Xiangyang#; Xiao, Yu; Yin, Zixi; Yang, Nengcong; Bao, Yunfeng; Zhu, Xunjin; Jin, Shengye; Feng, Zhaochi; Zhang, Fuxiang*, Water-stable nickel metal-organic framework nanobelts for cocatalyst-free photocatalytic water splitting to produce hydrogen. Journal of the American Chemistry Society 144, 2747-2754 (2022).
5. Li, Sha; Lin, Jiande; Ding, Yu; Xu, Pan; Guo, Xiangyang*; Xiong, Weiming; Wu, Deyin; Dong, Quanfeng; Chen, Jiajia*; Zhang, Li*, Defects engineering of lightweight metal-organic frameworks-based electrocatalytic membrane for high-loading lithium-sulfur batteries. ACS Nano 15, 13803-13813 (2021).
6. Guo, Xiangyang; Liu, Lifang; Xiao, Yu; Mehmood, Rashid; Xiao, Yejun; Qi, Yu; Zhang, Fuxiang*, Water-stable cobalt-based MOF for water oxidation in neutral aqueous solution: A case of mimicking the photosystem II. Inorganic Chemistry 60, 1790-1796 (2021).
7. Guo, Xiangyang; Xiao Yu; Liu Lifang; Qi Yu; Duan Chunyng; Zhang Fuxiang*, Band gap engineering of metal-organic frameworks for solar fuel productions. Coordination Chemistry Reviews 435, 213785 (2021).
8. Xiao, Yu#; Guo, Xiangyang#; Yang, Nengcong; Zhang, Fuxiang*, Heterostructured MOFs photocatalysts for water splitting to produce hydrogen. Journal of Energy Chemistry 58, 508–522 (2021).
9. Zhang, Tiexin#; Guo, Xiangyang#; Shi, Yusheng; He, Cheng; Duan, Chunying*, Dye-incorporated coordination polymers for direct photocatalytic trifluoromethylation of aromatics at metabolically susceptible positions. Nature Communications 9, 4024 (2018).
10.Guo, Xiangyang; Zhou, Zhen; Chen, Cong; Bai, Junfeng; He, Cheng; Duan, Chunying*, New rht-type metal-organic frameworks decorated with acylamide groups for efficient carbon dioxide capture and chemical fixation from raw power plant flue gas. ACS Applied Materials and Interfaces 8, 31746-31756 (2016).